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Topic Name: Black Carbon, a Form of Particulate Air Pollution Keeps a Great Role for Warming Effect in the Atmosphere

Category: Environmental engineering

Research persons: V. Ramanathan, Greg Carmichael

Location: Scripps Institution of Oceanography at UC San Diego, United States

Details

Black carbon, a form of particulate air pollution most often produced from biomass burning, cooking with solid fuels and diesel exhaust, has a warming effect in the atmosphere three to four times greater than prevailing estimates, according to scientists in an upcoming review article in the journal Nature Geoscience.

Scripps Institution of Oceanography at UC San Diego atmospheric scientist V. Ramanathan and University of Iowa chemical engineer Greg Carmichael, said that soot and other forms of black carbon could have as much as 60 percent of the current global warming effect of carbon dioxide, more than that of any greenhouse gas besides CO2. The researchers also noted, however, that mitigation would have immediate societal benefits in addition to the long term effect of reducing greenhouse gas emissions.

The article, “Global and regional climate changes due to black carbon,” will be posted in the online version of Nature Geoscience on Sunday, March 23.

“Observationally based studies such as ours are converging on the same large magnitude of black carbon heating as modeling studies from Stanford, Caltech and NASA,” said Ramanathan. “We now have to examine if black carbon is also having a large role in the retreat of arctic sea ice and Himalayan glaciers as suggested by recent studies.”

In the paper, Ramanathan and Carmichael integrated observed data from satellites, aircraft and surface instruments about the warming effect of black carbon and found that its forcing, or warming effect in the atmosphere, is about 0.9 watts per meter squared. That compares to estimates of between 0.2 watts per meter squared and 0.4 watts per meter squared that were agreed upon as a consensus estimate in a report released last year by the Intergovernmental Panel on Climate Change (IPCC), a U.N.-sponsored agency that periodically synthesizes the body of climate change research.

Ramanathan and Carmichael said the conservative estimates are based on widely used computer model simulations that do not take into account the amplification of black carbon’s warming effect when mixed with other aerosols such as sulfates. The models also do not adequately represent the full range of altitudes at which the warming effect occurs. The most recent observations, in contrast, have found significant black carbon warming effects at altitudes in the range of 2 kilometers (6,500 feet), levels at which black carbon particles absorb not only sunlight but also solar energy reflected by clouds at lower altitudes.

Between 25 and 35 percent of black carbon in the global atmosphere comes from China and India, emitted from the burning of wood and cow dung in household cooking and through the use of coal to heat homes. Countries in Europe and elsewhere that rely heavily on diesel fuel for transportation also contribute large amounts.

“Per capita emissions of black carbon from the United States and some European countries are still comparable to those from south Asia and east Asia,” Ramanathan said.

In south Asia, pollution often forms a prevalent brownish haze that has been termed the “atmospheric brown cloud.” Ramanathan’s previous research has indicated that the warming effects of this smog appear to be accelerating the melt of Himalayan glaciers that provide billions of people throughout Asia with drinking water. In addition, the inhalation of smoke during indoor cooking has been linked to the deaths of an estimated 400,000 women and children in south and east Asia.

Elimination of black carbon, a contributor to global warming and a public health hazard, offers a nearly instant return on investment, the researchers said. Black carbon particles only remain airborne for weeks at most compared to carbon dioxide, which remains in the atmosphere for more than a century. In addition, technology that could substantially reduce black carbon emissions already exists in the form of commercially available products.

Ramanathan said that an observation program for which he is currently seeking corporate sponsorship could dramatically illustrate the benefits. Known as Project Surya, the proposed venture would provide some 20,000 rural Indian households with smoke-free cookers and equipped to transmit data. At the same time, a team of researchers led by Ramanathan would observe air pollution levels in the region to measure the effect of the cookers.

Carmichael said he hopes that the paper’s presentation of the immediacy of the benefits will make it easier to generate political and regulatory momentum toward reduction of black carbon emissions.

“It offers a chance to get better traction for implementing strategies for reducing black carbon,” he said.

Note for Biomass
Biomass refers to living and recently dead biological material that can be used as fuel or for industrial production. Most commonly, biomass refers to plant matter grown for use as biofuel, but it also includes plant or animal matter used for production of fibres, chemicals or heat. Biomass may also include biodegradable wastes that can be burnt as fuel. It excludes organic material which has been transformed by geological processes into substances such as coal or petroleum.
Biomass is grown from several plants, including miscanthus, switchgrass, hemp, corn, poplar, willow, sugarcane and oil palm (palm oil). The particular plant used is usually not very important to the end products, but it does affect the processing of the raw material. Production of biomass is a growing industry as interest in sustainable fuel sources is growing.
Although fossil fuels have their origin in ancient biomass, they are not considered biomass by the generally accepted definition because they contain carbon that has been "out" of the carbon cycle for a very long time. Their combustion therefore disturbs the carbon dioxide content in the atmosphere.
Plastics from biomass, like some recently developed to dissolve in seawater, are made the same way as petroleum-based plastics, are actually cheaper to manufacture and meet or exceed most performance standards. But they lack the same water resistance or longevity as conventional plastics.
Biomass which is not simply burned as fuel may be processed in other ways such as corn.
Low tech processes include:
composting (to make soil conditioners and fertilizers)
anaerobic digestion (decaying biomass to produce methane gas and sludge as a fertilizer)
fermentation and distillation (both produce ethyl alcohol)
More high-tech processes are:
Pyrolysis (heating organic wastes in the absence of air to produce gas and char. Both are combustible.)
Hydrogasification (produces methane and ethane)
Hydrogenation (converts biomass to oil using carbon monoxide and steam under high pressures and temperatures)
Destructive distillation (produces methyl alcohol from high cellulose organic wastes).
Acid hydrolysis (treatment of wood wastes to produce sugars, which can be distilled)
Burning biomass, or the fuel products produced from it, may be used for heat or electricity production.
Other uses of biomass, besides fuel and compost include:
Building materials
Biodegradable plastics and paper (using cellulose fibres)
Biomass is part of the carbon cycle. Carbon from the atmosphere is converted into biological matter by photosynthesis. On death or combustion the carbon goes back into the atmosphere as carbon dioxide. This happens over a relatively short timescale and plant matter used as a fuel can be constantly replaced by planting for new growth. Therefore a reasonably stable level of atmospheric carbon results from its use as a fuel. It is commonly accepted that the amount of carbon stored in dry wood is approximately 50% by weight.

Though biomass is a renewable fuel, and is sometimes called a "carbon neutral" fuel, its use can still contribute to global warming. This happens when the natural carbon equilibrium is disturbed; for example by deforestation or urbanization of green sites. When biomass is used as a fuel, as a replacement for fossil fuels, it still puts the same amount of CO2 into the atmosphere, and is not a solution to global warming.

Note for Solid Fuel
Solid fuel refers to various types of solid material that are used as fuel to produce energy and provide heating, usually released through combustion. Solid fuels include wood (see wood fuel), charcoal, peat, coal, Hexamine fuel tablets, and pellets made from wood, corn, wheat, rye and other grains. Solid-fuel rocket technology also uses solid fuel.

Solid fuels have long been used by humanity to create fire. Coal was the fuel source which enabled the industrial revolution, from firing furnaces, to running steam engines. Wood was also extensively used to run steam locomotives. Both peat and coal are still used in electricity generation today.

The use of some solid fuels (eg. coal) is restricted or prohibited in some urban areas, due to unsafe levels of toxic emissions. The use of other solid fuels such as wood is increasing as heating technology and the availability of good quality fuel improves. In some areas, smokeless coal is often the only solid fuel used. In Ireland, peat briquettes are used as smokeless fuel. They are also used to start a coal fire.

Note for Global Warming
Global warming is the increase in the average temperature of the Earth's near-surface air and oceans since the mid-twentieth century and its projected continuation.

The global average air temperature near the Earth's surface rose 0.74 ± 0.18 °C (1.33 ± 0.32 °F) during the hundred years ending in 2005. The Intergovernmental Panel on Climate Change (IPCC) concludes "most of the observed increase in globally averaged temperatures since the mid-twentieth century is very likely due to the observed increase in anthropogenic greenhouse gas concentrations" via the greenhouse effect. Natural phenomena such as solar variation combined with volcanoes probably had a small warming effect from pre-industrial times to 1950 and a small cooling effect from 1950 onward. These basic conclusions have been endorsed by at least thirty scientific societies and academies of science, including all of the national academies of science of the major industrialized countries. While individual scientists have voiced disagreement with some findings of the IPCC, the overwhelming majority of scientists working on climate change agree with the IPCC's main conclusions.

Climate model projections summarized by the IPCC indicate that average global surface temperature will likely rise a further 1.1 to 6.4 °C (2.0 to 11.5 °F) during the twenty-first century. The range of values results from the use of differing scenarios of future greenhouse gas emissions as well as models with differing climate sensitivity. Although most studies focus on the period up to 2100, warming and sea level rise are expected to continue for more than a thousand years even if greenhouse gas levels are stabilized. The delay in reaching equilibrium is a result of the large heat capacity of the oceans.

Increasing global temperature will cause sea level to rise, and is expected to increase the intensity of extreme weather events and to change the amount and pattern of precipitation. Other effects of global warming include changes in agricultural yields, trade routes, glacier retreat, species extinctions and increases in the ranges of disease vectors.

Remaining scientific uncertainties include the amount of warming expected in the future, and how warming and related changes will vary from region to region around the globe. Most national governments have signed and ratified the Kyoto Protocol aimed at reducing greenhouse gas emissions, but there is ongoing political and public debate worldwide regarding what, if any, action should be taken to reduce or reverse future warming or to adapt to its expected consequences.

The term "global warming" is a specific example of global climate change. The term "climate change" can also refer to other periods of overall temperature change such as global cooling. In common usage, the term "global warming" refers to the warming in recent decades and implies a human influence. The United Nations Framework Convention on Climate Change (UNFCCC) uses the term "climate change" for human-caused change, and "climate variability" for other changes. The term "anthropogenic global warming" is sometimes used when focusing on human-induced changes.

The Earth's climate changes in response to external forcing, including variations in its orbit around the Sun (orbital forcing), volcanic eruptions, and atmospheric greenhouse gas concentrations. The detailed causes of the recent warming remain an active field of research, but the scientific consensus is that the increase in atmospheric greenhouse gases due to human activity caused most of the warming observed since the start of the industrial era. This attribution is clearest for the most recent 50 years, for which the most detailed data are available. Some other hypotheses departing from the consensus view have been suggested to explain the temperature increase. One such hypothesis proposes that warming may be the result of variations in solar activity.

Note for Greenhouse Gases
Greenhouse gases are components of the atmosphere that contribute to the greenhouse effect. Without the greenhouse effect the Earth would be uninhabitable; in its absence, the mean temperature of the earth would be about −19 °C (−2 °F, 254 K) rather than the present mean temperature of about 15 °C (59 °F, 288 K). Greenhouse gases include, in order of relative abundance: water vapour, carbon dioxide, methane, nitrous oxide, ozone and CFCs. Greenhouse gases come from natural sources and human activity; present CO2 levels are 380 ppmv, approximately 100 ppmv higher than they were in pre-industrial times.

When sunlight reaches the surface of the Earth, some of it is absorbed and warms the surface. Because the Earth's surface is much cooler than the sun, it radiates energy at much longer wavelengths than the sun does, peaking in the infrared at about 10µm. The atmosphere absorbs these longer wavelengths more effectively than it does the shorter wavelengths from the sun. The absorption of this longwave radiant energy warms the atmosphere; the atmosphere also is warmed by transfer of sensible and latent heat from the surface. Greenhouse gases also emit longwave radiation both upward to space and downward to the surface. The downward part of this longwave radiation emitted by the atmosphere is the "greenhouse effect." The term is a misnomer, as this process is not the mechanism that warms greenhouses.

The major greenhouse gases are water vapor, which causes about 36–70% of the greenhouse effect on Earth (not including clouds); carbon dioxide, which causes 9–26%; methane, which causes 4–9%, and ozone, which causes 3–7%. It is not possible to state that a certain gas causes a certain percentage of the greenhouse effect, because the influences of the various gases are not additive. (The higher ends of the ranges quoted are for the gas alone; the lower ends, for the gas counting overlaps.) Other greenhouse gases include, but are not limited to, nitrous oxide, sulfur hexafluoride, hydrofluorocarbons, perfluorocarbons and chlorofluorocarbons.

The major atmospheric constituents (nitrogen, N2 and oxygen, O2) are not greenhouse gases. This is because homonuclear diatomic molecules such as N2 and O2 neither absorb nor emit infrared radiation, as there is no net change in the dipole moment of these molecules when they vibrate. Molecular vibrations occur at energies that are of the same magnitude as the energy of the photons on infrared light. Heteronuclear diatomics such as CO or HCl absorb IR; however, these molecules are short-lived in the atmosphere owing to their reactivity and solubility. As a consequence they do not contribute significantly to the greenhouse effect.

Late 19th century scientists experimentally discovered that N2 and O2 did not absorb infrared radiation (called, at that time, "dark radiation") and that CO2 and many other gases did absorb such radiation. It was recognized in the early 20th century that the known major greenhouse gases in the atmosphere caused the earth's temperature to be higher than it would have been without the greenhouse gases.

The National Science Foundation, the National Oceanic and Atmospheric Administration and the National Aeronautics and Space Administration funded the review.

Scripps Institution of Oceanography, at UC San Diego, is one of the oldest, largest and most important centers for global science research and graduate training in the world. The National Research Council has ranked Scripps first in faculty quality among oceanography programs nationwide. Now in its second century of discovery, the scientific scope of the institution has grown to include biological, physical, chemical, geological, geophysical and atmospheric studies of the earth as a system. Hundreds of research programs covering a wide range of scientific areas are under way today in 65 countries. The institution has a staff of about 1,300, and annual expenditures of approximately $140 million from federal, state and private sources. Scripps operates one of the largest U.S. academic fleets with four oceanographic research ships and one research platform for worldwide exploration.

In figure 1, Scripps Climate and Atmospheric Science Professor V. Ramanathan

In figure 2, The polluting effects of cooking using biomass like wood or cow dung in south Asia are illustrated through a measurement of aerosol optical depth, a way of measuring the quantity of pollutants in the air by the relative ability of light to penetrate through them. This representation shows reconstructed levels of pollution from 2004 and 2005 with the effects of biofuel cooking removed.

In figure 3, The polluting effects of cooking using biomass like wood or cow dung in south Asia are illustrated through a measurement of aerosol optical depth, a way of measuring the quantity of pollutants in the air by the relative ability of light to penetrate through them. This representation shows reconstructed levels of pollution from 2004 and 2005.